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Sensitivity Analysis of Electrochemical Double Layer Approximations on Electrokinetic Predictions: Case Study for CO Reduction on Copper

https://doi.org/10.1021/acs.jpcc.4c01457

Wong, Andrew Jark-Wah; Tran, Bolton; Agrawal, Naveen; Goldsmith, Bryan R; Janik, Michael J (July 2024, The Journal of Physical Chemistry C)

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An efficient approach to compartmentalize double layer effects on kinetics of interfacial proton-electron transfer reactions

https://doi.org/10.1016/j.jcat.2024.115360

Agrawal, Naveen; Wong, Andrew Jark-Wah; Maheshwari, Sharad; Janik, Michael J (February 2024, Journal of Catalysis)

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Deconvoluting charge-transfer, mass transfer, and ohmic resistances in phosphonic acid–sulfonic acid ionomer binders used in electrochemical hydrogen pumps

https://doi.org/10.1039/D3EE01776A

Arunagiri, Karthik; Wong, Andrew Jark-Wah; Briceno-Mena, Luis; Elsayed, Hania Mohamed; Romagnoli, José A.; Janik, Michael J.; Arges, Christopher G. (January 2023, Energy & Environmental Science)

This work reveals how electrode binders affect reaction kinetics, ionic conductivity, and gas transport in electrochemical hydrogen pumps (EHPs). Using a blend of phosphonic acid and perfluorosulfonic acid ionomers as the electrode binder, an EHP was operated at 5 A cm⁻².
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